The development of new materials is a vital to meet the challenges faced by battery technologies. Ionic conducting solid polymer electrolytes could reduce the risk of explosion with non-flammability and high thermal stability. The use of solid polymer electrolyte is the additional strength of the electrodes performances to increase the number of cycle for the rechargeable batteries. In the present study, preparation of PVdF-HFP/PEMA blend based solid polymer electrolytes enclosure of two different plasticizers such as propylene carbonate (PC) and diethyl carbonate (DEC) at different concentrations and the accumulation of lithium perchlorate as salt. To confirm the structural changes and complex formations, the prepared electrolytes were subjected into XRD and FTIR analyses, and the porous nature of the electrolytes was identified using scanning electron microscopy. AC impedance studies were performed at various temperatures from 303 K to 363K for the prepared samples. The results suggest that the PC/DEC (1:1) based electrolyte exhibited the higher ionic conductivity is 0.00477 S/cm at room temperature and 0.00843 S/cm at 363K. The temperature dependence of ionic conductivity also complies with the VTF relation.
| Published in |
International Journal of Energy and Power Engineering (Volume 4, Issue 5-1)
This article belongs to the Special Issue Energy Systems and Developments |
| DOI | 10.11648/j.ijepe.s.2015040501.13 |
| Page(s) | 17-21 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2015. Published by Science Publishing Group |
Solid Polymer Electrolyte, FTIR, XRD, SEM, Conductivity
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APA Style
P. Sivakumar, M. Gunasekaran. (2015). Highly Porous Polymer Electrolytes Based on PVdF-HFP / PEMA with Propylene Carbonate/Diethyl Carbonate for Lithium Battery Applications. International Journal of Energy and Power Engineering, 4(5-1), 17-21. https://doi.org/10.11648/j.ijepe.s.2015040501.13
ACS Style
P. Sivakumar; M. Gunasekaran. Highly Porous Polymer Electrolytes Based on PVdF-HFP / PEMA with Propylene Carbonate/Diethyl Carbonate for Lithium Battery Applications. Int. J. Energy Power Eng. 2015, 4(5-1), 17-21. doi: 10.11648/j.ijepe.s.2015040501.13
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Download@article{10.11648/j.ijepe.s.2015040501.13,
author = {P. Sivakumar and M. Gunasekaran},
title = {Highly Porous Polymer Electrolytes Based on PVdF-HFP / PEMA with Propylene Carbonate/Diethyl Carbonate for Lithium Battery Applications},
journal = {International Journal of Energy and Power Engineering},
volume = {4},
number = {5-1},
pages = {17-21},
doi = {10.11648/j.ijepe.s.2015040501.13},
url = {https://doi.org/10.11648/j.ijepe.s.2015040501.13},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijepe.s.2015040501.13},
abstract = {The development of new materials is a vital to meet the challenges faced by battery technologies. Ionic conducting solid polymer electrolytes could reduce the risk of explosion with non-flammability and high thermal stability. The use of solid polymer electrolyte is the additional strength of the electrodes performances to increase the number of cycle for the rechargeable batteries. In the present study, preparation of PVdF-HFP/PEMA blend based solid polymer electrolytes enclosure of two different plasticizers such as propylene carbonate (PC) and diethyl carbonate (DEC) at different concentrations and the accumulation of lithium perchlorate as salt. To confirm the structural changes and complex formations, the prepared electrolytes were subjected into XRD and FTIR analyses, and the porous nature of the electrolytes was identified using scanning electron microscopy. AC impedance studies were performed at various temperatures from 303 K to 363K for the prepared samples. The results suggest that the PC/DEC (1:1) based electrolyte exhibited the higher ionic conductivity is 0.00477 S/cm at room temperature and 0.00843 S/cm at 363K. The temperature dependence of ionic conductivity also complies with the VTF relation.},
year = {2015}
}
TY - JOUR T1 - Highly Porous Polymer Electrolytes Based on PVdF-HFP / PEMA with Propylene Carbonate/Diethyl Carbonate for Lithium Battery Applications AU - P. Sivakumar AU - M. Gunasekaran Y1 - 2015/09/02 PY - 2015 N1 - https://doi.org/10.11648/j.ijepe.s.2015040501.13 DO - 10.11648/j.ijepe.s.2015040501.13 T2 - International Journal of Energy and Power Engineering JF - International Journal of Energy and Power Engineering JO - International Journal of Energy and Power Engineering SP - 17 EP - 21 PB - Science Publishing Group SN - 2326-960X UR - https://doi.org/10.11648/j.ijepe.s.2015040501.13 AB - The development of new materials is a vital to meet the challenges faced by battery technologies. Ionic conducting solid polymer electrolytes could reduce the risk of explosion with non-flammability and high thermal stability. The use of solid polymer electrolyte is the additional strength of the electrodes performances to increase the number of cycle for the rechargeable batteries. In the present study, preparation of PVdF-HFP/PEMA blend based solid polymer electrolytes enclosure of two different plasticizers such as propylene carbonate (PC) and diethyl carbonate (DEC) at different concentrations and the accumulation of lithium perchlorate as salt. To confirm the structural changes and complex formations, the prepared electrolytes were subjected into XRD and FTIR analyses, and the porous nature of the electrolytes was identified using scanning electron microscopy. AC impedance studies were performed at various temperatures from 303 K to 363K for the prepared samples. The results suggest that the PC/DEC (1:1) based electrolyte exhibited the higher ionic conductivity is 0.00477 S/cm at room temperature and 0.00843 S/cm at 363K. The temperature dependence of ionic conductivity also complies with the VTF relation. VL - 4 IS - 5-1 ER -
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