Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine

Ali Mohammed Yimer

doi:doi:10.11648/j.ajbio.s.2014020601.15

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Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine

Ali Mohammed Yimer

Published in American Journal of BioScience (Volume 2, Issue 6-1)

Received: 30 June 2014 Accepted: 14 July 2014 Published: 20 August 2014

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Abstract

The Schiff’s base ligands and their complexes with Ni(II), Cu(II) and Zn(II) were synthesized and characterized by elemental analysis molar conductivity, infrared and ultraviolet-visible spectroscopy and magnetic susceptibility measurements. The ligands, ethylenedianil of o-hydroxyphenylglyoxal, C18H16N2O4, have been synthesized by condensation of ethylenediamine and orthohydroxyphenylglyoxal. The metal complexes were prepared by mixing of saturated solutions of ligands and metal salts in appropriate molar ratio in acetone and methanol solvents. The study also confirmed the formation of mono-, di- and trinuclear isopolystructures of the complexes in square planar geometry except for Zn(II), which has tetrahedral stereochemistry. The synthesized ligands and their metal complexes were screened for their antimicrobial activities against two bacterial strains (Staphylococcus aureous and Xanthomonas holcicola), and two fungal strains (Aspergillus niger and Fusarium oxysporum) using a disc diffusion method. The tests showed that the complexes have higher antimicrobial activity than the free Schiff’s base.

Published in	American Journal of BioScience (Volume 2, Issue 6-1) This article belongs to the Special Issue Chemical Biology
DOI	10.11648/j.ajbio.s.2014020601.15
Page(s)	22-34
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Antimicrobial Studies, Disc Diffusion Method, Ethylenedianil of O-Hydroxyphenyl Glyoxal, Ortho-Hydroxyphenylglyoxal, Schiff’s Base, N,N-di (o-hydroxybenzenoylmethylene) ethylenediamine

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Ali Mohammed Yimer. (2014). Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine. American Journal of BioScience, 2(6-1), 22-34. https://doi.org/10.11648/j.ajbio.s.2014020601.15

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ACS Style

Ali Mohammed Yimer. Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine. Am. J. BioScience 2014, 2(6-1), 22-34. doi: 10.11648/j.ajbio.s.2014020601.15

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AMA Style

Ali Mohammed Yimer. Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine. Am J BioScience. 2014;2(6-1):22-34. doi: 10.11648/j.ajbio.s.2014020601.15

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@article{10.11648/j.ajbio.s.2014020601.15,
  author = {Ali Mohammed Yimer},
  title = {Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine},
  journal = {American Journal of BioScience},
  volume = {2},
  number = {6-1},
  pages = {22-34},
  doi = {10.11648/j.ajbio.s.2014020601.15},
  url = {https://doi.org/10.11648/j.ajbio.s.2014020601.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajbio.s.2014020601.15},
  abstract = {The Schiff’s base ligands and their complexes with Ni(II), Cu(II) and Zn(II) were synthesized and characterized by elemental analysis molar conductivity, infrared and ultraviolet-visible spectroscopy and magnetic susceptibility measurements. The ligands, ethylenedianil of o-hydroxyphenylglyoxal, C18H16N2O4, have been synthesized by condensation of ethylenediamine and orthohydroxyphenylglyoxal. The metal complexes were prepared by mixing of saturated solutions of ligands and metal salts in appropriate molar ratio in acetone and methanol solvents. The study also confirmed the formation of mono-, di- and trinuclear isopolystructures of the complexes in square planar geometry except for Zn(II), which has tetrahedral stereochemistry. The synthesized ligands and their metal complexes were screened for their antimicrobial activities against two bacterial strains (Staphylococcus aureous and Xanthomonas holcicola), and two fungal strains (Aspergillus niger and Fusarium oxysporum) using a disc diffusion method. The tests showed that the complexes have higher antimicrobial activity than the free Schiff’s base.},
 year = {2014}
}

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TY  - JOUR
T1  - Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine
AU  - Ali Mohammed Yimer
Y1  - 2014/08/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ajbio.s.2014020601.15
DO  - 10.11648/j.ajbio.s.2014020601.15
T2  - American Journal of BioScience
JF  - American Journal of BioScience
JO  - American Journal of BioScience
SP  - 22
EP  - 34
PB  - Science Publishing Group
SN  - 2330-0167
UR  - https://doi.org/10.11648/j.ajbio.s.2014020601.15
AB  - The Schiff’s base ligands and their complexes with Ni(II), Cu(II) and Zn(II) were synthesized and characterized by elemental analysis molar conductivity, infrared and ultraviolet-visible spectroscopy and magnetic susceptibility measurements. The ligands, ethylenedianil of o-hydroxyphenylglyoxal, C18H16N2O4, have been synthesized by condensation of ethylenediamine and orthohydroxyphenylglyoxal. The metal complexes were prepared by mixing of saturated solutions of ligands and metal salts in appropriate molar ratio in acetone and methanol solvents. The study also confirmed the formation of mono-, di- and trinuclear isopolystructures of the complexes in square planar geometry except for Zn(II), which has tetrahedral stereochemistry. The synthesized ligands and their metal complexes were screened for their antimicrobial activities against two bacterial strains (Staphylococcus aureous and Xanthomonas holcicola), and two fungal strains (Aspergillus niger and Fusarium oxysporum) using a disc diffusion method. The tests showed that the complexes have higher antimicrobial activity than the free Schiff’s base.
VL  - 2
IS  - 6-1
ER  -

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Ali Mohammed Yimer

Department of Chemistry, College of Natural Sciences, Arba Minch University, Ethiopia

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Ali Mohammed Yimer. (2014). Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine. American Journal of BioScience, 2(6-1), 22-34. https://doi.org/10.11648/j.ajbio.s.2014020601.15

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ACS Style

Ali Mohammed Yimer. Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine. Am. J. BioScience 2014, 2(6-1), 22-34. doi: 10.11648/j.ajbio.s.2014020601.15

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AMA Style

Ali Mohammed Yimer. Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine. Am J BioScience. 2014;2(6-1):22-34. doi: 10.11648/j.ajbio.s.2014020601.15

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@article{10.11648/j.ajbio.s.2014020601.15,
  author = {Ali Mohammed Yimer},
  title = {Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine},
  journal = {American Journal of BioScience},
  volume = {2},
  number = {6-1},
  pages = {22-34},
  doi = {10.11648/j.ajbio.s.2014020601.15},
  url = {https://doi.org/10.11648/j.ajbio.s.2014020601.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajbio.s.2014020601.15},
  abstract = {The Schiff’s base ligands and their complexes with Ni(II), Cu(II) and Zn(II) were synthesized and characterized by elemental analysis molar conductivity, infrared and ultraviolet-visible spectroscopy and magnetic susceptibility measurements. The ligands, ethylenedianil of o-hydroxyphenylglyoxal, C18H16N2O4, have been synthesized by condensation of ethylenediamine and orthohydroxyphenylglyoxal. The metal complexes were prepared by mixing of saturated solutions of ligands and metal salts in appropriate molar ratio in acetone and methanol solvents. The study also confirmed the formation of mono-, di- and trinuclear isopolystructures of the complexes in square planar geometry except for Zn(II), which has tetrahedral stereochemistry. The synthesized ligands and their metal complexes were screened for their antimicrobial activities against two bacterial strains (Staphylococcus aureous and Xanthomonas holcicola), and two fungal strains (Aspergillus niger and Fusarium oxysporum) using a disc diffusion method. The tests showed that the complexes have higher antimicrobial activity than the free Schiff’s base.},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Chemical Synthesis, Spectral Characterization and Antimicrobial Studies on Complexes of Ni(II), Cu(II) and Zn(II) with N, N-di (o-hydroxybenzenoylmethylene) Ethylenediamine
AU  - Ali Mohammed Yimer
Y1  - 2014/08/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ajbio.s.2014020601.15
DO  - 10.11648/j.ajbio.s.2014020601.15
T2  - American Journal of BioScience
JF  - American Journal of BioScience
JO  - American Journal of BioScience
SP  - 22
EP  - 34
PB  - Science Publishing Group
SN  - 2330-0167
UR  - https://doi.org/10.11648/j.ajbio.s.2014020601.15
AB  - The Schiff’s base ligands and their complexes with Ni(II), Cu(II) and Zn(II) were synthesized and characterized by elemental analysis molar conductivity, infrared and ultraviolet-visible spectroscopy and magnetic susceptibility measurements. The ligands, ethylenedianil of o-hydroxyphenylglyoxal, C18H16N2O4, have been synthesized by condensation of ethylenediamine and orthohydroxyphenylglyoxal. The metal complexes were prepared by mixing of saturated solutions of ligands and metal salts in appropriate molar ratio in acetone and methanol solvents. The study also confirmed the formation of mono-, di- and trinuclear isopolystructures of the complexes in square planar geometry except for Zn(II), which has tetrahedral stereochemistry. The synthesized ligands and their metal complexes were screened for their antimicrobial activities against two bacterial strains (Staphylococcus aureous and Xanthomonas holcicola), and two fungal strains (Aspergillus niger and Fusarium oxysporum) using a disc diffusion method. The tests showed that the complexes have higher antimicrobial activity than the free Schiff’s base.
VL  - 2
IS  - 6-1
ER  -

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